Search results for "Sorbic Acid"

showing 5 items of 5 documents

Biological Monitoring of Exposure to Benzene in Port Workers

2020

Port workers are exposed to a wide range of occupational hazards that can cause injuries and occupational diseases. Among these, exposure to benzene is one of the most important but least studied. The highest occupational exposures for port workers occur during the filling and loading of gasoline, and cleaning of tanks and receptacles. The aim of the study was to evaluate occupational exposure to low levels of benzene by measuring trans,trans-muconic acid (t,t-MA) in urine samples from workers operating at fuelling stations in a tourist port of Southern Italy. The overall sample was composed of 43 port workers of a tourist port in Southern Italy. In 2018, each participant provided two (morn…

AdultEveningtUrineUrinalysist-muconic acidToxicologybenzene03 medical and health scienceschemistry.chemical_compound0302 clinical medicineHumansMedicine030212 general & internal medicineport workerBenzenePersonal protective equipmentOriginal ResearchMorningSmokerCreatinineSmokersbusiness.industrylcsh:Public aspects of medicine030503 health policy & servicesUrinalysiport workersPublic Health Environmental and Occupational Healthlcsh:RA1-1270Non-SmokersBiomarkeroccupational exposureMiddle AgedPort (computer networking)Sorbic AcidItalybiological monitoringchemistryNon-SmokerCreatininePublic HealthOccupational exposure0305 other medical sciencebusinessBiomarkersHumanFrontiers in Public Health
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ChemInform Abstract: Trienediolates of Hexadienoic Acids in Synthesis. Synthesis of Retinoic and nor-Retinoic Acids.

2010

Abstract Double deprotonation of either (E,E)-3-methyl-2,4-hexadienoic acid 2, or 4,6-dimethyldihydro-2-pyrone 3 generates apparently the same lithium trienediolate, which affords ω-hydroxy acids 9 on reaction with ketones 7. Hydroxy acids 9 are easily dehydrated to octatrienoic acids 5, which are structurally related to retinoic acid. Similarly, sorbic acid 1 leads to nor-retinoic acid analogs 6.

chemistry.chemical_compoundAddition reactionDeprotonationchemistryRetinoic acidchemistry.chemical_elementLithiumGeneral MedicineSorbic acidMedicinal chemistryChemInform
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Polyenolates of unsaturated carboxylic acids in synthesis. A straightforward synthesis of retinoic acids.

1990

Abstract Retinoic acids are prepared in a two step procedure by addition of lithium trienediolates of sorbic acid and 3-methyl-sorbic acid to β-ionone.

chemistry.chemical_classificationchemistry.chemical_compoundChemistryOrganic ChemistryDrug DiscoveryTwo stepFatty acidchemistry.chemical_elementOrganic chemistryLithiumSorbic acidBiochemistryTetrahedron Letters
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Trienediolates of hexadienoic acids in synthesis. synthesis of retinoic and nor-retinoic acids.

1993

Abstract Double deprotonation of either (E,E)-3-methyl-2,4-hexadienoic acid 2, or 4,6-dimethyldihydro-2-pyrone 3 generates apparently the same lithium trienediolate, which affords ω-hydroxy acids 9 on reaction with ketones 7. Hydroxy acids 9 are easily dehydrated to octatrienoic acids 5, which are structurally related to retinoic acid. Similarly, sorbic acid 1 leads to nor-retinoic acid analogs 6.

chemistry.chemical_classificationAddition reactionKetoneChemistryOrganic ChemistryRetinoic acidBiochemistrychemistry.chemical_compoundDeprotonationDrug DiscoveryOrganic chemistryStereoselectivityAliphatic compoundSorbic acidAcetophenoneTetrahedron
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Studies on the induction of gene mutations in bacterial and mammalian cells by the ring-opened benzene metabolites trans,trans-muconaldehyde and tran…

1990

t,t-Muconaldehyde and t,t-muconic acid have been investigated for the induction of gene mutations in Salmonella typhimurium (reversion of the his- strains TA97, TA98, TA100, TA102, TA104 and TA1535), Escherichia coli (reversion of the trp- strain WP2 uvrA) and Chinese hamster V79 cells (acquisition of resistance toward 6-thioguanine). t,t-Muconaldehyde proved weakly mutagenic in strain TA104 in the presence and absence of NADPH-fortified postmitochondrial fraction from rat liver homogenate (S9 mix). In strains TA97, TA100 and TA102, weak positive responses were observed only in the presence of S9 mix. In strains TA98, TA1535 and WP2 uvrA, the result was negative. In V79 cells, the mutation …

MaleMuconic acidHealth Toxicology and MutagenesisGene mutationBiologyToxicologymedicine.disease_causeAmes testchemistry.chemical_compoundCricetulusCricetinaeGeneticsmedicineEscherichia coliAnimalsMutation frequencyEscherichia coliGenetics (clinical)Cells CulturedAldehydesHydroquinoneMutagenicity TestsBenzeneRats Inbred Strainsbiology.organism_classificationEnterobacteriaceaeSorbic AcidRatschemistryBiochemistryMutationFatty Acids UnsaturatedBacteriaMutagensMutagenesis
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